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Phosphoric acid is a medium-strength tribasic inorganic acid with little oxidising power, so it does not promote the passive film on stainless steel the way nitric acid does. Selection is made directly from concentration, temperature and impurity content. 316L is common in ambient dilute acid, while hotter or stronger acid moves to 2205 duplex, 904L or non-metallic materials. Wet-process acid often carries fluoride and sulphate impurities that change the corrosion behaviour.
Because phosphoric acid is not oxidising, stainless steel cannot rely on passivation and its resistance depends on the grade itself and the duty window.
| Location | Material / process | Basis |
| Ambient dilute acid | 316L stainless steel | Resistant and cost-effective at low concentration and temperature |
| Medium temperature or higher concentration | 2205 duplex or 904L | Better pitting and uniform corrosion resistance |
| Hot concentrated acid or fluoride impurities | PVDF / PP / FRP non-metallic | Avoids localised attack and fluoride erosion |
| Impeller | 316L, 2205 or PP / PVDF, integrally formed | Wetted parts in direct contact with the medium |
| Sealing | PTFE or fluoroelastomer seal | Resists phosphoric acid and stops acid mist leakage |
| Location | Material / process | Basis |
| Weld treatment | Post-weld pickling, passivation and grinding | Reduces weld sensitisation and crevice attack |
| Fasteners | 316L or coated bolts | Prevents fasteners corroding first |
| Drain and wash | Low point drain and wash connection | Limits acid and impurity residue |
| Motor isolation | Anti-corrosion baffle between motor and casing | Protects motor insulation |
| Fluoride handling | Non-metallic lining isolation | Wet-process fluoride attacks metal and glass phases |
Wet- and thermal-process phosphoric acid production, phosphate and compound fertiliser plants, metal phosphating treatment, pre-electroplating treatment and food-grade phosphoric acid dosing, wherever phosphoric acid or its mist is handled.
Wet-process phosphoric acid often carries fluoride and sulphate impurities, and condensed acid mist is more aggressive, so liquid pooling and dead corners must be avoided.
Phosphating baths run warmer with fluctuating concentration, so selection must be checked against the actual bath composition and temperature. Where hydrochloric or hydrofluoric acid is also present, the rules for phosphoric acid no longer apply.
| Standard | Title | Purpose |
| HG/T 20679 | Design code for external anti-corrosion of chemical equipment and piping | Anti-corrosion design for chemical media |
| GB/T 4237 | Hot rolled stainless steel plate, sheet and strip | Stainless impeller and casing material |
| GB/T 20878 | Stainless and heat-resisting steels - Designation and chemical composition | High temperature and corrosion resistant grades |
| GB/T 1236 | Industrial fans - Performance testing using standardized airways | Air flow, pressure and efficiency testing |
| GB/T 10178 | Industrial fans - Performance testing in situ | On-site performance verification |
Please provide the phosphoric acid concentration range, medium temperature, whether fluoride impurities are present and the air flow. Size and motor power are calculated for the actual duty.
Phosphoric acid is a medium-strength reducing acid, so it does not promote passivation of stainless steel and resistance depends on grade, concentration and temperature. 316L suits only ambient dilute acid; hotter or stronger acid moves to 2205 duplex or PVDF / PP non-metallic materials.
No. Wet-process acid often carries fluoride and sulphate impurities, and fluoride attacks metals and glass phases, so PVDF, PP, FRP or higher alloys are preferred. Thermal-process acid has fewer impurities and a wider metal selection window.
Welds and impeller roots. Crevices and weld slag residues corrode first, so establish the inspection interval during the first year through visual inspection and thickness measurement.
Related pages: Anti-corrosion fan range Sulphuric acid resistant centrifugal fan Hydrochloric acid resistant centrifugal fan
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